When we try to send some data to an external web service (REST, POST, JSON), we get the next error:
System.CalloutException: sun.security.validator.ValidatorException: PKIX path building failed: sun.security.provider.certpath.SunCertPathBuilderException: unable to find valid certification path to requested target
If we check the certificate, it's a valid "Go Daddy Secure Certificate Authority - G2".
Also, We have checked that this company is included as a valid Certificate Authority into Salesforce list (https://developer.salesforce.com/page/Outbound_Messaging_SSL_CA_Certificates#godaddy).