I am trying to emulate the below view in LWC. The description value "Click here for Email Template" should only be hyperlink not the entire value, the value is passed from the apex class. Can anyone help me out how to reach this requirement in LWC.
You can create a custom component and add it to the datatable via custom data type. You will also have to create a component to extend the datatable. This answer helps outline that How to use custom LWC lightning component in lightning-datatable
Creating Custom Data Types https://developer.salesforce.com/docs/component-library/bundle/lightning-datatable/documentation